Gluten-Free Brioche - Modernist Cuisine

Gluten-Free Brioche

Recipe • March 12, 2025

 

There are thousands upon thousands of kinds of leavened breads in the world, but only a handful of types—injera and dosa, for example—are gluten-free by nature. The others rely on gluten for their elasticity and structure. That means making a gluten-free loaf of bread is a very difficult endeavor—after all, the familiar structure and texture of bread is defined by gluten. Because they lack the signature texture of wheat-based breads, gluten-free loaves are technically more like savory cakes than breads.

For us, creating a successful version of gluten-free bread means replicating the consistency of traditional bread and trying to make our experimental gluten-free loaves as bread-like as we can. While this process is not without challenges, we believe our recipes come very close to achieving our goal. We’ve come up with a blend of flours and then add thickening agents and enzymes to make loaves that resemble regular bread as closely as possible.

Even if you’re not gluten-free, learning to bake a gluten-free loaf is a valuable skill—perfect for making something special for a friend or family member who is.

Gluten-free brioche is a great place to start. Brioche is the granddaddy of sweet enriched breads; it’s rich and tender (and deeply satisfying) because it’s laden with butter. The richness of butter and eggs provides gluten-free dough (which is typically dense) with some welcome softness. For this recipe, the hydration level is slightly lower than it would be for a wheat-flour dough. This is to ensure that the dough is easy to work with given that there is no gluten to contribute structure. Many of our tasters did not know this brioche was gluten-free—it’s that good.


Recipe


 

Additional Tips

  • If you are using an aluminum or steel pan, lightly and evenly coat the interior surface with cooking spray, and then either coat it with the gluten-free flour blend (tap out the excess) or line it with parchment paper or a baking pan paper cup made to fit your specific pan.
  • We recommend using a stand mixer with a paddle attachment to mix this dough, which has the consistency of paste.
  • If you can’t find osmotolerant yeast, you can use instant dry yeast and increase the final proofing time by 20–30 minutes.
  • Baking on a baking stone or steel will produce a better oven spring and a shorter baking time for the bread.
  • Baking times can vary. The best way to make sure the bread is baked is to check its core temperature, which should read 90–93°C / 195–200°F.
  • If you would like to warm-proof your dough, you can proof it at 27°C / 80°F for 2–3 hours.
  • Transglutaminase is typically used to bind meat proteins to each other (it is often used in sausage making). But we found that it also binds the proteins in this flour blend. We tested transglutaminase to see whether it would act the same way as gluten does when added to a weak flour dough. While we didn’t get any volume increase, we did notice a chew and consistency to the crumb that made it much more like wheat bread.
  • If you use transglutaminase in your gluten-free flour blend, you will have to freeze the entire quantity of the blend because the enzymes in the transglutaminase do not survive for long at room temperature. If you do freeze the flour mix, pull what you need from the freezer, and let it warm up at room temperature for 1–2 hours before you mix your dough.
  • We recommend toasting any of our gluten-free breads.
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